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Compare the reaction between 2,4,6 -cycloheptatrienone and cyclopentadiene to the reaction between 2,4,6-cycloheptatrienone and ethene. Why does 2,4,6-cycloheptatrienone use two πelectrons in one reaction and four πelectrons in the other? | Numerade
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The primary orbital interactions in the transition state of normal Diels-Alder reactions occur between the highest occupied molecular orbital (the HOMO) of the diene and the lowest unoccupied molecular orbital (the LUMO) of the dienophile; however, in so-called inverse demand Diels-Alder reactions, the primary orbital interactions occur between the LUMO of the diene and the HOMO of the dienophile. a. The four π-molecular orbitals for 1,3-cyclopentadiene are shown below. Show how each of the orbi
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SOLVED: Draw reaction energy diagram showing both reactions on the same reaction coordinate: (Remember to label appropriate features of diagram: Assume reactants are of similar energy:) Construct BRIEF CONCISE explanation, using your diagram for why pKa of cyclopentadiene is lower than the pKa of cyclohexene He -HO pKa= 43 pKa=
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