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SOLVED: Question 13 (4 points) The Lewis structures for a benzene molecule is illustrated below:This illustration represents that the:intramolecular bonds in the molecule are of equal length and that the electronic distribution of charge within each of the bonds are identical:molecule exists in two distinct formssingle bonds within the molecule have longer length than the double bond in the moleculebenzene molecule exists 50% of the time in one form ad the other 50% of time in the other form.
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SOLVED:(a) For a long time attempts to prepare compound A were thwarted by its ready isomerization to compound B. The isomerization is efficiently catalyzed by traces of base. Write a reasonable mechanism for this isomerization. Compound A Compound B (b) Another attempt to prepare compound A by hydrolysis of its diethyl acetal gave only the 1,4 -dioxane derivative C. How was compound C formed?
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SOLVED:One of the later steps in glucose biosynthesis is the isomerization of fructose 6-phosphate to glucose 6 -phosphate. Propose a mechanism, using acid or base catalysis as needed. (FIGURE CAN'T COPY)
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