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The primary orbital interactions in the transition state of normal Diels-Alder reactions occur between the highest occupied molecular orbital (the HOMO) of the diene and the lowest unoccupied molecular orbital (the LUMO) of the dienophile; however, in so-called inverse demand Diels-Alder reactions, the primary orbital interactions occur between the LUMO of the diene and the HOMO of the dienophile. a. The four π-molecular orbitals for 1,3-cyclopentadiene are shown below. Show how each of the orbi
The primary orbital interactions in the transition state of normal Diels-Alder reactions occur between the highest occupied molecular orbital (the HOMO) of the diene and the lowest unoccupied molecular orbital (the LUMO) of the dienophile; however, in so-called inverse demand Diels-Alder reactions, the primary orbital interactions occur between the LUMO of the diene and the HOMO of the dienophile. a. The four π-molecular orbitals for 1,3-cyclopentadiene are shown below. Show how each of the orbi
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