Examples of diols... | Filo
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I0. In the following reaction how many different diols, are for... | Filo
I0. In the following reaction how many different diols, are for... | Filo
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1,2-Diols are converted to carbonyl compounds when treated with strong acids, in a reaction called the pinacol rearrangement. (a) Draw a stepwise mechanism for this reaction. (Hint: The reaction proceeds by way of carbocation intermediates.) (b) Assuming that the pinacol rearrangement occurs via the more stable carbocation, draw the rearrangement product formed from diol D. | Numerade
1,2-Diols are converted to carbonyl compounds when treated with stron…
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1,2 diols form carbonyl compounds via the Pinacol Rearrangement. Propose a stepwise mechanism for this reaction. Details count; include all nonbonding electrons and formal charges! Add curved arrows. OH? ? H :ÖH :ÖH loss of H?O 12 loss of H? (as H?O?) ? Draw intermediate structure; add curved arrows. Omit H?O. Draw intermediate structure; add curved arrows. Draw intermediate structure; add curved arrows. Omit H?O. Draw intermediate structure; add curved arrows.
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Consider the two diols (1 and 2 ) and the two ketones (3 and 4). A mixture of 3 and 4 is formed by pinacol rearrangement of either 1 or 2. Given that an ethyl migrates in preference to methyl in pinacol rearrangements, predict the major ketone formed by rearrangement of each diol. Diol 1 gives predominantly Diol 2 gives predominantly A. Ketone 3 B. Ketone 4
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Both 1,2 -diols and 1,3 -diols can be protected by treatment wi... | Filo
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Of the foilowing diols which reacts with \mathrm{CrO}{3} in aqu... | Filo
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